You should start at ISO 100 when using the Sunny 16 rule.
A stop is a term used in every aspect of photography to represent a relative change in the brightness of
light. One stop is double the amount of light you had previously.
How many stops brighter is a room if you start with one lightbulb and then add another? One Stop.
All of the settings that represent a "Full Stop" of light.:
f/0.7 f/1.0 f/1.4 f/2 f/2.8 f/4 f/5.6 f/8 f/11 f/16 f/22 f/32 f/45 f/64 f/90 f/128 f/180 f/256
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